Effectiveness of Calcium Carbonate in Chicken Eggshell as a Copper Adsorbent in Kotagede Silver Craft Liquid Waste

Article Sidebar

PDF
Issue
Vol. 21 No. 2 (2024): Jurnal Kesehatan Lingkungan Volume 21 No. 2, Juli 2024
Published: Jul 1, 2024
Keywords:
Eggshell,
Calcium carbonate,
Adsorption,
Heavy metal Cu

Main Article Content

Silmi Aziza Karroghi
Universitas Diponegoro Semarang
Nurjazuli Nurjazuli
Universitas Diponegoro Semarang
Tri Joko
Universitas Diponegoro Semarang

Abstract

The silver craft industry’s liquid waste contains hazardous heavy metals such as Cu. Waste containing Cu is directly discharged into the environment, harming the environment and living organisms. An alternative treatment for this liquid waste is the adsorption method using activated chicken eggshells, which have a high CaCO3 content as an adsorbent. This study aims to determine the effectiveness of chicken eggshell adsorbents in reducing Cu levels in silver craft liquid waste solutions. The research employs a quasi-experimental method. The dependent variable in this study is the Cu content in the silver craft liquid waste. In contrast, the independent variables are adsorbent particle size with variations of 50 mesh, 100 mesh, and 150 mesh and adsorbent concentrations with variations of 30 g/L, 40 g/L, and 50 g/L. The statistical test used is the General Linear Model (GLM). The results showed that eggshell adsorbents could reduce Cu levels by 80.82% (from 2.671 mg/L to 0.512 mg/L), which occurred in the particle size group of 150 mesh and a concentration of 40 g/L. However, this result has yet to effectively reduce Cu levels below the standard (0.5 mg/L) stipulated by DIY Regional Regulation No. 7 of 2016. Data analysis with the GLM test showed a significant difference in Cu levels based on variations in adsorbent particle size (p-value=0.000) and adsorbent concentration (p-value=0.024). The interaction between particle size and adsorbent concentration did not show a significant difference (p-value=0.810), indicating it did not reduce Cu levels effectively.

Article Details

Section
Articles
Creative Commons License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

(CC BY-SA) : This license allows to Share — copy and redistribute the material in any medium or format, Adapt — remix, transform, and build upon the material, for any purpose, even commercially.

The copyright of the received article shall be assigned to the journal as the publisher of the journal. The intended copyright includes the right to publish the article in various forms (including reprints). The journal maintains the publishing rights to the published articles.

Authors are permitted to disseminate published articles by sharing the link/DOI of the article at the journal. Authors are allowed to use their articles for any legal purposes deemed necessary without written permission from the journal with an acknowledgment of initial publication to this journal.

References

​1. Sekarwati N. Dampak Logam Berat Tembaga dan Perak pada Limbah Cair Industri Perak Terhadap Kualitas Air Sumur di Kotagede Yogyakarta. 2016;9(1):477–89.

Giyatmi, Fallihah T, Swantomo D. Penurunan Kadar Cu dalam Limbah Cair Industri Perak Menggunakan Adsorben Abu Layang. Seminar Nasional Soebardjo Brotohardjono XVI. 2020;1–7.

Prakoso NI. Application of Lignin as Adsorbent for Silver (Ag) and Copper (Cu) on Electroplating Waste in Kota Gede. Indonesian Journal of Chemical Research. 2018;3(1):20–7.

Damarswasty LR, Wahyuning Widiarti I, Renata Ade Yudono A. Kajian Kerentanan Kualitas Air Tanah Terhadap Potensi Pencemaran Industri Kerajinan Logam di Yogyakarta. Jurnal Ilmiah Lingkungan Kebumian. 2022;4(1):34–46.

Maslahat M, Taufiq A, Wahyu Subagja P. Pemanfaatan Limbah Cangkang Telur sebagai Biosorben untuk Adsorpsi Logam Pb dan Cd. Jurnal Sains Natural Universitas Nusa Bangsa. 2015;5(1):92–100.

Sumiati, Erwan E, Purnamasari DK, Syamsuhaidi S, Suhartini S. Potensi Kerabang Telur dalam Pakan Ayam Ras Telur Telur. Junal Sains Teknologi dan Lingkungan [Internet]. 2021;287–96. Available from: https://doi.org/10.29303/jstl.v0i0.281

Fitriyana, Safitri E. Pemanfaatan Cangkang Telur Ayam Sebagai Adsorben Untuk Meningkatkan Kualitas Minyak Jelantah. Konversi. 2015;4(1):12–6.

Ratnasari ND, Moelyaningrum AD, Ellyke. Penurunan Kadar Tembaga (Cu) pada Limbah Cair Industri Elektroplating menggunanakan Cangkang Telur Ayam Potong Teraktivasi Termal. Sanitasi: Jurnal Kesehatan Lingkungan. 2017;9(2):56–62.

Inamuddin, Ahamed MI, Lichtfouse E, Asiri AM (eds). Environmental Chemistry for a Sustainable World: Green Adsorbents to Remove Metals, Dyes and Boron from Polluted Water. Springer; 2021.

Syauqiah I, Insan Kusuma F, Yani Km JA, Selatan K. Adsorption of Zn and Pb Metal in Printing Waste of PT. Grafika Wangi Kalimatan Using Corn Cobs Charcoal as Adsorbent. Konversi. 2020;9(1):28–34.

Ismadji S, Soetardjo FE, Santoso SP, Putro JN, Yuliana M, Irawati W. Adsorpsi pada Fase Cair. Surabaya: Universitas Katolik Widya Mandala; 2021.

Astuti W. Adsorpsi Menggunakan Material Berbasis Lignoselulosa. Semarang: Unnes Press; 2018.

Nadeak S, Hasibuan JM, Naibaho LW, Sinaga MS. Pemanfaatan Limbah Cangkang Telur Ayam Sebagai Adsorben pada Pemurnian Gliserol dengan Metode Asidifikasi dan Adsorpsi. Jurnal Teknik Kimia USU. 2019;8(1):25–31.

Hajar EWI, Sitorus RS, Mulianingtias N, Welan FJ. Efektivitas Adsorpsi Logam Pb2+ dan Cd2+ Menggunakan Media Adsorben Cangkang Telur Ayam. Konversi. 2016;5(1):1–8.

Haryono, Natael CL, Rukiah, Yulianti YB. Kalsium Oksida Mikropartikel dari Cangkang Telur sebagai Katalis pada Sintesis Biodiesel dari Minyak Goreng Bekas. Jurnal Material dan Energi Indonesia. 2018;8(1):8–15.

Pardede EP, Mularen A. Pemurnian Minyak Jelantah Menggunakan Adsorben Berbasis Cangkang Telur. Atmosphere (Basel). 2020;1(1):8–16.

Amanah IN, Indriyani FIP, Asriza RO. Pengaruh Jenis Asam pada Aktivasi Cangkang Telur sebagai Adsorben Logam Cu pada Air Kolong [Internet]. In: Seminar Nasional Penelitian dan Pengabdian pada Masyarakat. 2022. page 117–22. Available from: https://mail.journal.ubb.ac.id/snppm/article/view/3747/2033

Wijayanti Kusuma B, Endah Wahyuningsih N, Budiyono. Efektivitas Kalsium Karbonat dengan Variasi Ketebalan Media dalam Mengurangi Kadar Kadmium pada Larutan Pupuk. Jurnal Kesehatan Masyarakat. 2018;6(6):2356–3346.

Thilagan J, Kumar AV, Rajasekaran K, Raja C. Continuous Fixed Bed Column Adsorption of Copper (II) Ions from Aqueous Solution by Calcium Carbonate. International Journal of Engineering Research & Technology (IJERT). 2015;4(12):413–8.

Said NI. Teknologi Pengolahan Air Limbah: Teori dan Aplikasi. Jakarta: Erlangga; 2017.

Bertus MYP, Suherman, Sabang SM. Karakterisasi FTIR Poliblend Serbuk Biji Buah Kelor (Moringa oleifera) dan Cangkang Ayam Ras untuk Pengolahan Air Gambut di Daerah Palu Barat. Jurnal Akademika Kimia. 2014;3(1):243–51.

Novianti, Fitria L, Kadaria U. Potensi Cangkang Telur Ayam sebagai Media Filter untuk Meningkatkan pH pada Pengolahan Air Gambut. Jurnal Teknologi Lingkungan Lahan Basah. 2019;7(2):64–71.

Hanafi, Zahara TA, Yusuf W. Optimasi Filter Cangkang Kerang Darah (Anadara granosa) untuk Meningkatkan pH Air Gambut. Jurnal Teknologi Lingkungan Lahan Basah. 2016;4(1):1-10.

Shafirinia R, Wardana IW, Oktiawan W. Pengaruh Variasi Ukuran Adsorben dan Debit Aliran terhadap Penurunan Khrom (Cr) dan Tembaga (Cu) dengan Arang Aktif dari Limbah Kulit Pisang pada Limbah Cair Industri Pelapisan Logam (Elektroplating) Krom. Jurnal Teknik Lingkungan. 2016;5(1):1–9.

Lestari NC, Budiawan I, Fuadi AM. Pemanfaatan Cangkang Telur dan Sekam Padi sebagai Bioadsorben Metilen Biru pada Limbah Tekstil. Jurnal Riset Kimia. 2021;12(1):36–43.

Nurlaili T, Kurniasari L, Ratnani DR. Pemanfaatan Limbah Cangkang Telur Ayam sebagai Adsorben Zat Warna Methyl Orange dalam Larutan. Inovasi Teknik Kimia. 2017;2(2):11–4.

Maharani V, Kuntjoro S, Indah NK. Pemanfaatan Serbuk Cangkang Telur Ayam sebagai Adsorben Logam Berat Kadmium (Cd) pada Limbah Cair Industri Batik Jetis Sidoarjo. LenteraBio. 2018;7(1):39–44.

Nurafriyanti, Prihatini NS, Syauqiah I. Pengaruh Variasi pH dan Berat Adsorben dalam Pengurangan Konsentrasi Cr Total pada Limbah Artifisial Menggunakan Adsorben Ampas Daun Teh. Jukung (Jurnal Teknik Lingkungan). 2017;3(1):56–65.

Auliah IN. Efektivitas Penurunan Kadar Besi (Fe) pada Air Sumur dengan Filtrasi Serbuk Cangkang Kerang Variasi Diameter Serbuk. Jurnal Penelitian Kesehatan Suara Forikes. 2019;10(1):25–33.

Fundneider T, Acevedo Alonso V, Abbt-Braun G, Wick A, Albrecht D, Lackner S. Empty Bed Contact Time: The Key for Micropollutant Removal in Activated Carbon Filters. Water Res. 2021; 191:1–11.

Moona N, Holmes A, Wünsch UJ, Pettersson TJR, Murphy KR. Full-scale manipulation of the Empty Bed Contact Time to Optimize Dissolved Organic Matter Removal by Drinking Water Biofilters. ACS ES&T Water. 2021;1(5):1117–26.